منابع مشابه
Optical basicity of ionic liquids.
The concept of optical basicities initially developed by Duffy for solid oxides was successfully transferred to low melting salts such as ionic liquids (ILs). Several ionic liquids (ILs) were doped with Mn(NTf(2))(2) (NTf(2) = bis(trifluoromethanesulfonyl)imide) as a probe to investigate the IL anion basicity by means of UV-Vis spectroscopy. The (6)A(1)-->(4)A, (4)E(G) transition band of Mn(2+)...
متن کاملOptical Basicity and Polarizability of Nd3+-Doped Bismuth Borate Glasses
This paper reports on different physical and optical properties of Nd3+-doped bismuth borate glasses. The glasses containing Nd3+ in (25 − x)Bi2O3:20Li2O:20ZnO:35B2O3:xNd2O3 (where x = 1, 1.5, 2 mol%) have been prepared by melt-quenching method. The amorphous nature of the glasses was confirmed by X-ray diffraction studies. The physical parameters like dielectric constant, refractive index, ion...
متن کاملOptical basicity scales in protic solvents: water, hydrogen fluoride, ammonia and their mixtures.
In an inorganic material, a measure of the Lewis basicity of a solvent is commonly provided by the optical basicity, i.e. the ability of the solvent molecules to donate their electrons to an acidic species. This quantity is known to vary with the polarizability of the Lewis base. In protic solvents, the Lewis definition of basicity is barely used; it is replaced by the more purpose-built Brønst...
متن کاملPhotoswitchable basicity through the use of azoheteroarenes.
Azoheteroarene photoswitches offer functional advantages over their more conventional azobenzene counterparts by virtue of their heteroaromatic ring(s). Here we report that azobis(2-imidazole) functions as a photoswitchable base due to the additional proton stabilisation that is possible in the protonated Z isomer, facilitated by the basic imidazole nitrogens. This thermodynamic difference in s...
متن کاملBrønsted basicity of the air-water interface.
Differences in the extent of protonation of functional groups lying on either side of water-hydrophobe interfaces are deemed essential to enzymatic catalysis, molecular recognition, bioenergetic transduction, and atmospheric aerosol-gas exchanges. The sign and range of such differences, however, remain conjectural. Herein we report experiments showing that gaseous carboxylic acids RCOOH(g) begi...
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ژورنال
عنوان ژورنال: Bulletin of the Japan Institute of Metals
سال: 1986
ISSN: 0021-4426,1884-5835
DOI: 10.2320/materia1962.25.3